Anywhere from 30 min before to the start of your workout should be fine, I think. BCAAs won't be your body's first source of energy, so you're more likely to metabolize them for energy later in the workout. It also depends on what kind of workout you're doing. If it's strength oriented, then you could probably take it at the start...or just whenever. If you're doing something like I am or something like DC training, then you might want to take it 30 min before.

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